Mineralien / Minerals / Minerales > Systematik und Klassifikation / Systematics and Classification

CancrinitSodalith Supergruppe

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Günter Blaß:
Hallo,
habe ich zufällig unter Neue Mineralien hier im Atlas gefunden (CancrinitSodalith Supergruppe).

Ist das ein Verschreiber oder gibt es zu dieser Supergruppe auch Literatur?
Wenn ja welche und kann man davon ein Exemplar bekommen?

MfG u. GA
Günter Blaß

Stefan:
Hallo Günter,

hatte ich vergessen einzufügen.

Bonaccorsi E.; Ballirano P. Camara F.  - Microporous and Mesoporous Materials - Volume 147, Issue 1, January 2012, Pages 318–326; The crystal structure of sacrofanite, the 74 Å phase of the cancrinite–sodalite supergroup


Abstract: Sacrofanite, a = 12.903(2) angstrom, c = 74.284(8) angstrom, space group P (6) over bar 2c, belongs to the cancrinite-sodalite super-group of minerals, and displays a 28-layer stacking sequence along the c axis. Its stacking sequence is ABCABACACABACBACBACABABACABC ... , where A. B and C stand for the positions of six-member rings of tetrahedra in each layer. It corresponds to the Zhdanov symbol vertical bar 12(8)21 vertical bar 12(8)21 vertical bar, and gives rise to a framework with topological symmetry P6(3)/mmc. The ordering of Si and Al in the tetrahedral sites reduces the symmetry to P (6) over bar 2c. The members of this supergroup of minerals belong to the wider ABC-6 family, where also double rings of tetrahedra may occur. They share many structural features with zeolites, showing structural cages hosting extra-framework ions as well as H2O molecules. The crystal structure of sacrofanite has been modelled on the basis of High Resolution Transmission Electron Microscopy (HRTEM) images. The resulting model has been successfully refined by using both single-crystal synchrotron radiation and laboratory data. The refinements converged to R = 0.083 for 4228 unique reflections, and to R = 0.096 for 15,795 unique reflections, respectively. The resulting framework is formed by eight cancrinite and four sodalite cages superimposed along [0, 0, z], whereas one cancrinite, four sodalite, two losod, and one liottite cages occur along [1/3, 2/3, z] and [2/3, 1/3, z]. The structural formula of sacrofanite, as obtained from the refinement and by crystal chemical considerations, is (Na61K19Ca32)(Sigma-112)(Si84Al84O336)(SO4)(26)Cl(2)F6 center dot 2H(2)O.


Grüße Stefan

Stefan:
Auch hier ist einiges zu der Gruppe zu finden:

Paolo Ballirano -The thermal behaviour of liottite - Physics and Chemistry of Minerals February 2012, Volume 39, Issue 2, pp 115-121

http://link.springer.com/article/10.1007/s00269-011-0466-8  (Klick auf Look inside)

Paolo Ballirano - Haüyne: mutual cations/anionic groups arrangement and thermal expansion mechanism - Physics and Chemistry of Minerals October 2012, Volume 39, Issue 9, pp 733-747

http://link.springer.com/article/10.1007/s00269-011-0466-8 (Klick auf Look inside)

Günter Blaß:
Hallo Stefan,

vielen Dank für die Informationen.
Werde mir die Literatur zu Gemüte führen.

Beste Grüße
Günter

Günter Blaß:
Hallo Stefan,

bei der Sodalith-Gruppe ist unter anderem auch Berzelianit aufgeführt.
Kann es sein, dass hier eine Verwechslung mit dem Synonym Berzeline für Berzelianit (nach Beudant) mit der Hauyn- Varietät Berzeline (nach Necker) vorliegt?

Schönen Sonntag
Günter Blaß

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