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Nalivkinite (Nalivkinit)

Pictures (2 Images total)

Nalivkinit
Views (File:
1244720812
): 1246
Nalivkinit
Bildbreite: 30 mm; Fundort: Dara-i-Pioz-Gletscher, Alayskiy (Alai) Range, Tien-Shan-Gebirge, Tadschikistan
Copyright: Pavel M. Kartashov; Contribution: Philip Blümner
Location: Tadschikistan/Republik-unterstellte Gebiete (Nohijahoi tobei Dschumhurij)/Dara-i-Pioz (Darai-Pioz)
Mineral: Nalivkinite
Image: 1244720812
Rating: 4 (votes: 1)
License: Usage for Mineralienatlas project only
Nalivkinit

Bildbreite: 30 mm; Fundort: Dara-i-Pioz-Gletscher, Alayskiy (Alai) Range, Tien-Shan-Gebirge, Tadschikistan
Copyright: Pavel M. Kartashov
Contribution: Philip Blümner 2009-06-11
Locality: Dara-i-Pioz (Darai-Pioz) / Republik-unterstellte Gebiete (Nohijahoi tobei Dschumhurij) / Tadschikistan
Nalivkinit
Views (File:
1264107395
): 726
Nalivkinit
Größe: 12x10 mm; Fundort: Dara-i-Pioz-Gletscher, Alayskiy (Alai) Range, Tien-Shan-Gebirge, Tadschikistan
Copyright: Paul Bongaerts; Contribution: Philip Blümner
Location: Tadschikistan/Republik-unterstellte Gebiete (Nohijahoi tobei Dschumhurij)/Dara-i-Pioz (Darai-Pioz)
Mineral: Nalivkinite
Image: 1264107395
Rating: 4 (votes: 1)
License: Usage for Mineralienatlas project only
Nalivkinit

Größe: 12x10 mm; Fundort: Dara-i-Pioz-Gletscher, Alayskiy (Alai) Range, Tien-Shan-Gebirge, Tadschikistan
Copyright: Paul Bongaerts
Contribution: Philip Blümner 2010-01-21
Locality: Dara-i-Pioz (Darai-Pioz) / Republik-unterstellte Gebiete (Nohijahoi tobei Dschumhurij) / Tadschikistan

Collectors Summary

Crystal System triklin, P1

Chemism

Chemical formula

Li2NaFe2+7Ti2Si8O26(OH)4F

Empirical formula (analysis)

(Li1.14K0.75Cs0.09Pb0.02)Σ2 (Na0.71Ca0.29)Σ1 (Fe2+5.62Mn0.90Zr0.08Na0.08Mg0.04Zn0.04)Σ6.76 (Ti1.56Nb0.24Sn0.09Zr0.08Ta0.04)Σ2 [(Si7.86Al0.15)Σ8.01 O24]O2(OH)4F[(H2O)1.14☐0.86]Σ2

Chemical composition

Eisen, Lithium, Natrium, Silicium, Titan, Fluor, Sauerstoff, Wasserstoff

Unit weight: 1327.8479091766 u; Number of atoms in the formula: 59.06

Info

Empirical formula:

(Li1.14K0.75Cs0.09Pb0.02)(Na0.71Ca0.29)(Fe5.62Mn0.90Zr0.08Na0.08Mg0.04Zn0.04)(Ti1.56Nb0.24Sn0.09Zr0.08Ta0.04)[(Si7.86Al0.15)O24]O2(OH)4F[(H2O)1.14Vc0.86]

Element

Symbol

Weight%

Atoms

Atoms%

Atom weight (u)

Sum weight (u)
Vacancy

Vc

0.00

0.86

1.46

0.0000000

0.0000000
Hydrogen

H

0.48

6.28

10.63

1.0079470

6.3299072
Lithium

Li

0.60

1.14

1.93

6.9412000

7.9129680
Oxygen

O

37.52

31.14

52.73

15.9994300

498.2222502
Fluorine

F

1.43

1

1.69

18.9984033

18.9984033
Sodium

Na

1.37

0.79

1.34

22.9897702

18.1619185
Magnesium

Mg

0.07

0.04

0.07

24.3050600

0.9722024
Aluminium

Al

0.30

0.15

0.25

26.9815382

4.0472307
Silicon

Si

16.62

7.86

13.31

28.0855300

220.7522658
Potassium

K

2.21

0.75

1.27

39.0983100

29.3237325
Calcium

Ca

0.88

0.29

0.49

40.0784000

11.6227360
Titanium

Ti

5.62

1.56

2.64

47.8671000

74.6726760
Manganese

Mn

3.72

0.9

1.52

54.9380499

49.4442449
Iron

Fe

23.64

5.62

9.52

55.8452000

313.8500240
Zinc

Zn

0.20

0.04

0.07

65.4094000

2.6163760
Zirconium

Zr

1.10

0.16

0.27

91.2242000

14.5958720
Niobium

Nb

1.68

0.24

0.41

92.9063820

22.2975317
Tin

Sn

0.80

0.09

0.15

118.7107000

10.6839630
Caesium

Cs

0.90

0.09

0.15

132.9054520

11.9614907
Tantalum

Ta

0.55

0.04

0.07

180.9479100

7.2379164
Lead

Pb

0.31

0.02

0.03

207.2100000

4.1442000

Analysis wt%

SiO2 : 36.11, Nb2O5 : 2.40, Ta2O5 : 0.61, TiO2 : 9.48, ZrO2 : 1.47, Al2O3 : 0.58, FeO : 30.84, MnO : 4.86, SnO : 0.89, Li2O : 1.30, CaO : 1.24, Na2O : 1.88, K2O : 2.68, Cs2O : 0.93, F : 1.45, H2O : 2.75 (Ref: Canadian Mineralogist 2008)

Strunz 9th edition incl. updates

9.DC.05

9: Silikate (Germanate)
D: Ketten- und Bandsilikate (Inosilikate)
C: Ketten- und Bandsilikate mit verzweigten 2-periodischen Einzelketten, Si2O6 + 2SiO3 -> Si4O12
05:Astrophyllit-Gruppe

Lapis Classification

VIII/G.12-010

VIII: SILIKATE
G: Übergangsstrukturen zwischen Ketten- und Schichtsilikaten
12: Astrophyllit-Gruppe

Classification by Hölzel

9.DU.570

9: SILICATES
D: Inosilicates; ~[Si2O6]4--...2-Chain
U: Chains to Phyllosilicates
5: Astrophyllite-Group

IMA status

anerkannt 12/2006

Mineral status

anerkanntes Mineral

IMA Classification

IMA Classification

 Astrophyllite supergroup  ⇒ Astrophyllite group

Crystallography

Crystal System

triklin

Class (H-M)

1

Space Group number

2

Space Group

P1

Cell parameters a (Å)

5.374(3)

Cell parameters b (Å)

11.948(5)

Cell parameters c (Å)

11.676(5)

Cell parameters a/b or c/a

0.45

Cell parameters c/b

0.977

Cell parameters α

113.360(6)°

Cell parameters β

94.538(8)°

Cell parameters γ

103.01(1)°

Z

1

Volume (ų)

658.592

X-Ray Powder Diffraction

10.56(100), 3.50(100), 2.780(80), 2.648(45), 2.578(70), 2.295(30), 2.106(35), 1.760(30)
XRD chart Nalivkinite

Calculated from d-spacing and intensity at 0.1541838 nm (Cu)

Crystal Structure 3D

Open larger view

Physical Properties

Density (g/cm³)

3.347 (berechnet)

3.348 ( ρ calc. Mineralienatlas )

(Co-)Type locality

(Co-)Type locality

Tadschikistan/Republik-unterstellte Gebiete (Nohijahoi tobei Dschumhurij)/Dara-i-Pioz (Darai-Pioz)

References

Agakhanov, A.A., Pautov, L.A., Sokolova, E., Abdu, Y.A., Karpenko, V.Y. - Two Astrophyllite-Supergroup Minerals: Bulgakite, A New Mineral From the Darai-Pioz Alkaline Massif, Tajikistan and Revision of the Crystal Structure and Chemical Formula of Nalivkinite. Canadian Mineralogist, 54 (2016), 33-48.

IMA group assignments

 
Astrophyllite supergroup
 
 
 

 
 
Astrophyllite group
 
 
 

 
 
 
Astrophyllite
K2Na(Fe2+,Mn)7Ti2[O2|F|(OH)4|Si8O24]
triklin
A1

 
 
 
Bulgakite
Li2(Ca,Na)Fe2+7Ti2(Si4O12)2O2(OH)4(F,O)(H2O)2
triklin
P1

 
 
 
Hydroastrophyllite
(H3O,K)2Ca(Fe2+,Mn)5-6Ti2[O2|F|(OH)4|Si8O24]
triklin
 

 
 
 
Nalivkinite
Li2NaFe2+7Ti2Si8O26(OH)4F
triklin
P1

 
 
 
Niobophyllite
K2NaFe2+7(Nb,Ti)2Si8O26(OH)4(F,O)
triklin
P1, P1

 
 
 
Tarbagataite
(K,☐)Ca(Fe2+,Mn)7Ti2(Si4O12)2O2(OH)5
triklin
P1

 
 
 
Zircophyllite
K2NaFe2+7Zr2(Si4O12)2O2(OH)4F
triklin
P1

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Actuality: 15. May 2025 - 05:12:04

Other languages

German

Nalivkinit

Spanish

Nalivkinita

English

Nalivkinite

Russian

Наливкинит

CNMNC (IMA)-Number

IMA 2006-038

CNMNC symbol

Symbol

Nlv

Locations with GPS information

IDs

GUSID (Global unique identifier short form) pJi1tvHEO0azh_k5jErCNA
GUID (Global unique identifier) B6B598A4-C4F1-463B-B387-F9398C4AC234
Database ID 4408